李郤里

一、个人情况

李郤里，男，1965年08月出生，江西省婺源县人，理学博士，教授，博士生导师

办公地点：郑州市高新区科学大道136号，郑州轻工业大学材料与化学工程学院270房间。

E-mail: lixl@zzuli.edu.cn               电话:   13503869487

二、教育背景

2008.06 博士毕业于南京大学化学化工学院，配位化学国家重点实验室

三、研究方向

手性分子基线性和非线性光学材料，手性分子磁体

四、承担课程及教学成果

国防与前沿材料

五、科研成果及奖励（项目、专利、奖励等）

项目：

1. 手性稀土晶态分子材料的非线性光学性能研究，河南省高等学校重点科研项目

专利：

1. 李郤里；周立明；王爱玲；崔明会；一种Dy(III)-Cu(II)共晶单分子磁体及其制备方法，2022-05-20，中国，ZL202010010015.1

2. 李郤里；王爱玲；朱灿灿；李俊锋；李凤彩；(–)-2-(4′,5′-蒎烯吡啶基-2′)吡嗪叠氮钴(III)配合物及其制备方法，2021-02-02，中国，ZL201811184453.9

3. 李郤里；周立明；王爱玲；朱灿灿；李俊锋；崔明会；(–)-2-(4′-吡啶基)-4,5-蒎烯-吡啶六氟乙酰丙酮铜配合物及其制备方法，2021-01-29，中国，ZL201811183587.9

4. 李郤里；周立明；王爱玲；朱灿灿；李俊锋；(–)-2-(4′,5′-蒎烯吡啶基-2′)吡嗪β-二酮钐配合物及其制备方法，2020-12-29，中国，ZL201811337430.7

5. 李郤里；周立明；魏剑英；王爱玲；朱灿灿；李俊锋；一种醋酸根桥联的手性双核铜配合物及其制备方法，2020-12-25，中国，ZL201811182671.9

6. 李郤里；朱灿灿；刘应凡；李凤彩；李俊锋；(–)-2-(4′-吡啶基)-4,5-蒎烯-吡啶手性银配合物及其制备方法，2020-12-22，中国，ZL201811266246.8

7. 李郤里；魏剑英；王爱玲；朱灿灿；李俊锋；荣麒翔；(+)-2,6-二(4,5-蒎烯-2-吡啶基)吡啶手性单核锰配合物及其制备方法，2020-05-29，中国，ZL201811183589.8

8. 李郤里；王爱玲；朱灿灿；李俊锋；李凤彩；(–)-2-(4′-吡啶基)-4,5-蒎烯-吡啶手性钴(II)配合物及其制备方法，2020-05-29，中国，ZL201811183879.2

获奖情况：

1. 新颖结构的有机配合物型转光剂的制备技术，河南省科学技术进步二等奖，2013-01。

六、发表论著（著作、发表文章等）

1. Xi-Li Li,* Ailing Wang, Yanan Li, Congli Gao, Minghui Cui, Hong-Ping Xiao,* Liming Zhou,* Two Chiral Yb^III Enantiomeric Pairs with Distinct Enantiomerically Pure N-Donor Ligands Presenting Significant Differences in Photoluminescence, Circularly Polarized Luminescence, and Second-Harmonic Generation, Inorg. Chem. 2023, 62, 4351‒4360.

2. Xi-Li Li,* Yanan Li, Ailing Wang, Congli Gao, Minghui Cui, Cai-Ming Liu,* Liming Zhou,* Two temperature-induced 1D Cu^II chain enantiomeric pairs showing different magnetic properties and nonlinear optical responses, Dalton Trans. 2023, 52, 2440‒2447.

3. Xiaodi Du,* Congli gao, Zhiqiang Zhang, Bing Su, Xi-Li Li,* A pair of ionic 1D Cu(II) chain enantiomers simultaneously displaying large second- and third-harmonic generation responses, Dalton Trans. 2023, 52, 13229–13234.

4. Xi-Li Li,* Ailing Wang, Minghui Cui, Congli Gao, Xiaojing Yu, Bing Su, Liming Zhou, Cai-Ming Liu,* Hong-Ping Xiao,* Yi-Quan Zhang,* Modulating Two Pairs of Chiral Dy^III Enantiomers by Distinc β-Diketone Ligands to Show Giant Differences in Single-Ion Magnet Performance and Nonlinear Optical Response, Inorg. Chem. 2022, 61, 9283−9294.

5. Congli Gao, Jianya Zhou, Minghui Cui, Diming Chen, Liming Zhou,* Fengcai Li, Xi-Li Li,* Distinct nonlinear optical responses in three pairs of 2D homochiral Ag(I) enantiomers modulated by dicarboxylic acid ligands, Inorg. Chem. Front. 2022, 9, 284–293.

6. Minghui Cui, Linpo Yang, Fengcai Li, Liming Zhou, Yanglin Song, Shao-Ming Fang,* Cai-Ming Liu, Xi-Li Li,* Multifunctional Dy^III Enantiomeric Pairs Showing Enhanced Photoluminescences and Third-Harmonic Generation Responses through the Coordination Role of Homochiral Tridentate N,N,N-Pincer Ligands, Inorg. Chem. 2021, 60, 13366−13375.

7. Minghui Cui, Ai-Ling Wang, Cong-Li Gao, Liming Zhou, Tao Wu,* Shaoming Fang, Hong-Ping Xiao,* Feng-Cai Li, Xi-Li Li,* Two homochiral Eu^III and Sm^III enantiomeric pairs showing circularly polarized luminescence, photoluminescence and triboluminescence. Dalton Trans. 2021, 50, 1007‒1018.

8. Minghui Cui, Ai-Ling Wang, Yingfan Liu, Hongping Xiao, Fengcai Li, Liming Zhou,* Shaoming Fang, Xi-Li Li,* A pair of 2D chiral Ag(I) enantiomers with dual chiral elements: syntheses, structures, and photoluminescent and chiroptical properties. RSC Adv. 2020, 10, 39359–39365.

9. Xi-Li Li,* Junfeng Li, Ailing Wang, Cai-Ming Liu,* Minghui Cui, Yi-Quan Zhang,* Observation of field-induced single-ion magnet behavior in a mononuclear Dy^III complex by co-crystallization of a square-planar Cu^II complex, Inorg. Chim. Acta 2020, 510, 119718.

10. Xi-Li Li,* Cancan Zhu, Qixiang Rong, Jiahao Wei, Ruixue Li, Cai-Ming Liu,* A pair of mononuclear Dy(III) enantiomers showing single-ion magnetic and ferroelectric properties, New J. Chem. 2018, 42, 10906–10911.

11. Xi-Li Li,* Junfeng Li, Cancan Zhu, Bing Han, Yingfan Liu, Zhigang Yin,* Fengcai Li, Cai-Ming Liu,* An intense luminescent Dy(III) single-ion magnet with the acylpyrazolonate ligand showing two slow magnetic relaxation processes, New J. Chem. 2018, 42, 16992–16998.

12. Xi-Li Li,* Ming Hu, Zhigang Yin, Cancan Zhu, Cai-Ming Liu,* Hong-Ping Xiao, Shaoming Fang,* Enhanced single-ion magnetic and ferroelectric properties of mononuclear Dy(III) enantiomeric pairs through the coordination role of chiral ligands, Chem. Commun. 2017, 53, 3998‒4001.